Cookies

Our site uses cookies to optimize the content and improve the performance. If you continue the browsing it will be considered that you accept that our webpage may be able to use your cookie files. For more information, please visit the "Privacy Policy" Privacy statement

Customize

Analytics Collect statistics data
Goal _ga, _gat, _gid, _gali
  • Home
  • Catalog
  • Chemical Biology
  • 1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]diphenylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]diphenylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
SDSDownload

1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]diphenylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate / 100 MG

Purity: 97 %
Synonym: ThrePHOX, Ubaphox; [((4S,5S)-Ph2-Ubaphox)Ir(COD)]BARF; ((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate
Molecular Formula: C77H58BF24IrNO2P
Molecular Weight: 1719.25
SKU: MND-54099
CAS Number: 405235-55-4
MDL number: MFCD06658140
Form: lumps
Note: Prices are for comparison only. Contact Sales for current pricing.
Packing size: 100 MG  
71.40 EUR

Properties

Flash Point (C)Not available
Flash Point (F)Not available

 Product Description

1,5-CYCLOOCTADIENE{[DIBENZYL((4S,5S)-5-METHYL-2-PHENYL-4,5-DIHYDRO-4-OXAZOLYL)METHYL]DIPHENYLPHOSPHINITE ΚN:ΚP}IRIDIUM(I) TETRAKIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)BORATE is a specialized iridium complex employed as a catalyst in organic synthesis reactions. Its unique structure, incorporating a chiral oxazoline ligand, enhances its efficiency in asymmetric catalysis.

 

Application:

Utilized as a catalyst in asymmetric catalysis, the complex enhances the efficiency of various organic synthesis reactions, making it valuable in the production of chiral compounds.

 

 

Articles:

- Threonine-Derived Phosphinite-Oxazoline Ligands for the Ir-Catalyzed Enantioselective Hydrogenation

Publication Date: 28 February 2002

Frederik Menges, Andreas Pfaltz

https://doi.org/10.1002/1615-4169(200201)344:1<40::AID-ADSC40>3.0.CO;2-7

 

-Iridium-Catalyzed H/D Exchange: Ligand Complexes with Improved Efficiency and Scope

Publication Date: 10 July 2014

Dr. Michael Parmentier, Dr. Thomas Hartung, Prof. Dr. Andreas Pfaltz, Dr. Dieter Muri

https://doi.org/10.1002/chem.201402078

 

-P-Stereogenic ligands: synthesis and application to asymmetric hydrogenation

Publication Date: 2-Nov-2022

Rojo Solé, Josep Maria

http://hdl.handle.net/2445/191368