1,3,5-Triaza-7-phosphaadamantane / 2 G

1,3,5-TRIAZA-7-PHOSPHAADAMANTANE is a chemical compound featuring a phosphorus atom bound to a nitrogen-rich adamantane framework. It is commonly used as a ligand in organometallic chemistry and catalysis.

Application:

1,3,5-TRIAZA-7-PHOSPHAADAMANTANE serves as a versatile ligand in transition metal catalysis, facilitating various organic transformations such as hydrogenation, cross-coupling, and asymmetric synthesis. It is also employed in the preparation of metal complexes for pharmaceutical and materials science applications.

Articles:

- Synthesis, characterization, and crystal structure of a quadruply bonded dimolybdenum(II) complex containing the water-soluble phosphine 1,3,5-triaza-7-phosphaadamantane (PTA)

Publication Date: Available online 22 November 2005

Brian J. Frost, Shawna B. Miller, Kyle O. Rove, David M. Pearson, Justin D. Korinek, Jennifer L. Harkreader, Charles A. Mebi, Jason Shearer

https://doi.org/10.1016/j.ica.2005.10.007

- Insights into the κ-P,N Coordination of 1,3,5-Triaza-7-phosphaadamantane and Derivatives: κ-P,N-Heterometallic Complexes and a 15N Nuclear Magnetic Resonance Survey

Publication Date: April 4, 2022

Andrés Alguacil, Franco Scalambra and Antonio Romerosa

https://doi.org/10.1021/acs.inorgchem.1c03831

- Water-Soluble Organometallic Compounds. 7.1 Further Studies of 1,3,5-Triaza-7-Phosphaadamantane Derivatives of Group 10 Metals, Including Metal Carbonyls and Hydrides

Publication Date: April 21, 1999

Donald J. Darensbourg, Jeffrey B. Robertson, David L. Larkins, and Joseph H. Reibenspies

https://doi.org/10.1021/ic981243j