trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene

Synonym: Danishefsky‘s diene; 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE; (E)-((4-methoxybuta-1,3-dien-2-yl)oxy)trimethylsilane
Molecular Formula: (CH3)3SiOC('=CH2)CH'=CHOCH3
Molecular Weight: 172.30
CAS Number: 54125-02-9
MDL number: MFCD00008498
Note: Prices are for comparison only. Contact Sales for current pricing.
Purity: 95 %
Packing size: 1 G  
Form: liquid  
47.25 EUR
Purity: 95 %
Packing size: 5 G  
Form: liquid  
168.00 EUR



Safety Information


Hazard Statements

H226

Precautionary Statements

P210
P233
P240
P241
P242
P243

Pictograms

 Product Description

Trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene is a chemical compound commonly used as a diene monomer in organic synthesis, particularly in the preparation of functionalized polymers and silicone-based materials.

 

Application:

This compound serves as a key building block in organic chemistry reactions, facilitating the formation of polymeric materials with diverse applications in industries such as adhesives, coatings, sealants, and biomedical materials.

 

 

Articles:

- Asymmetric aza-Diels-Alder reaction of Danishefsky's diene with imines in a chiral reaction medium

Publication Date: 18 Sep 2006

Bruce Pégot, Olivier Nguyen Van Buu,  Didier Gori and Giang Vo-Thanh

https://doi.org/10.1186/1860-5397-2-18

 

- Highly enantioselective formal aza-Diels–Alder reactions with acylhydrazones and Danishefsky's diene promoted by a silicon Lewis acid

Publication Date: Available online 15 March 2010

Sharon K. Lee, Uttam K. Tambar, Nicholas R. Perl, James L. Leighton

https://doi.org/10.1016/j.tet.2010.03.036

 

- Stepwise Bond Formation in Photochemical and Thermal Diels−Alder Reactions of C60 with Danishefsky's Dienes

Publication Date: February 23, 2000

Koichi Mikami, Shoji Matsumoto, Yasutaka Okubo, Mamoru Fujitsuka, Osamu Ito, Tomoyoshi Suenobu and Shunichi Fukuzumi

https://doi.org/10.1021/ja992848x