Nickel(II) chloride ethylene glycol dimethyl ether complex

Nickel(II) Chloride Ethylene Glycol Dimethyl Ether Complex is a coordination compound consisting of nickel chloride and ethylene glycol dimethyl ether (EGDM). This complex is notable for its ability to act as a catalyst in various chemical reactions, particularly those involving the reduction of carbonyl compounds. Its formation facilitates the activation of substrates, leading to increased reaction rates and selectivities in synthetic processes. The complex's stability and ease of handling make it a valuable tool in both academic and industrial research.

Application:

In the field of catalysis, Nickel(II) Chloride Ethylene Glycol Dimethyl Ether Complex is utilized for its efficiency in promoting redox reactions. Its use extends to the synthesis of fine chemicals, pharmaceuticals, and materials science, where it aids in the selective reduction of aldehydes and ketones to alcohols. The complex's versatility in catalyzing a wide range of reactions underscores its importance in the development of sustainable and efficient chemical transformations.

Articles:

- Electrochemically Driven Nickel-Catalyzed Halogenation of Unsaturated Halide and Triflate Derivatives

Publication Date: 06 November 2023

Ming-Yu Chen, Sylvain Charvet, Dr. Pierre-Adrien Payard, Dr. Marie-Eve L. Perrin, Dr. Julien C. Vantourout

https://doi.org/10.1002/anie.202311165

- Ni-Catalyzed Electrochemical C(sp2)−C(sp3) Cross-Coupling Reactions

Publication Date: 25 August 2020

Jian Luo ,Bo Hu ,wenda wu ,maowei hu ,Tianbiao Liu

https://doi.org/10.26434/chemrxiv.11813505.v2

- 1-Aryltriazenes in the Suzuki, Heck, and Sonogashira Reactions in Imidazolium-ILs, with [BMIM(SO3H)][OTf] or Sc(OTf)3 as Promoter, and Pd(OAc)2 or NiCl2·glyme as Catalyst

Publication Date: 26 August 2019

Suraj M. Sutar, Hemantkumar M. Savanur, Shruti S. Malunavar, Pavankumar Prabhala, Rajesh G. Kalkhambkar, Kenneth K. Laali

https://doi.org/10.1002/ejoc.201901070